个人简述:

历伟，副教授，硕士生导师

宁波大学聚烯烃产品工程课题组

欢迎有志青年报考攻读硕士研究生

科研条件

本课题组具有专业的金属有机合成和负载化技术力量。实验操作条件完备，包括气体、溶剂的精制系统、无水无氧操作、化学合成等。本实验室具备自行设计的高压淤浆聚合反应釜和高压气相聚合反应釜共4套，能够在线测定聚合动力学实验数据。

拥有高级流变拓展系统、高温凝胶色谱仪（配备三检测器，UHMWPE专用柱）、固液两用Bruker核磁共振仪，场发射扫描电镜、自制无水无氧XPS样品室，Minjet微挤出机、成套混炼设备、差示扫描量热仪、热重分析仪、漫反射红外光谱仪、超高速摄像机、动态力学性能分析仪器、万能试验机、小角X射线散射、偏光显微镜和接触角测试仪等表征设备。

科研工作:

先后在Chemical Communications(if 6.8)、Polymer(if 3.7)、IECR(if 2.2)、Journal of Polymer Science, Part A: Polymer Chemistry(if 4.1)等国际知名学术期刊发表论文20余篇，申请专利9项，已授权6项。近期已发表的论文主要有：

1. Xue B, Hui L, Yang HQ, Zhao YL, Hou LX*, Li W*, Immobilization of Ziegler-Natta catalyst for ethylene polymerization on macropores SiO2 with an open-framework structure, Ind. Eng. Chem. Res., 2017, 56, 135-142.

2. Li W*, Yang HQ, Zhang JJ, Mu JS, Gong DR, Wang XD, Immobilization of isolated FI catalyst on polyhedral oligomeric silsesquioxane-functionalized silica for the synthesis of weakly entangled polyethylene, Chem. Commun., 2016, 52,11092-11095.

3. Li W*, Yang HQ, Shang MY, Chen T, Wang WQ, Structural and morphological evolution of nascent polyethylene during ethylene in situ polymerization within Fe3O4@SiO2 nanoparticles, Ind. Eng. Chem. Res., 2016, 55, 8719-8725.

4. Chen P, Yang HQ, Chen T, Li W*, Weakly Entangled Ultrahigh Molecular Weight Polyethylene Prepared via Ethylene Extrusion Polymerization, Industrial & Engineering Chemistry Research, 2015, 54, 11024-11032.

5. Chen T, Yang HQ, Li W*, Phase structure and mechanical properties of disentangled ultra-high molecular weight polyethylene/polyhedral oligomeric silsesquioxane nanocomposites in a solid state, Journal of Polymer Research, 2015, 22, 223.

6. Li W*, Chen T, Guan C, Gong DR, Mu JS, Chen ZR, Zhou Q, Influence of Polyhedral Oligomeric Silsesquioxane Structure to the Disentangled State of Ultra High Molecular Weight Polyethylene Nanocomposites during Ethylene in situ Polymerization, Industrial & Engineering Chemistry Research, 2015, 54, 1478-1486.

7. Liu W, Pan WJ, Wang P, Li W, Mu JS, Weng GS, Jia XY, Gong DR*, Huang KW, Synthesis of mixed-ligand cobalt complexes and their applications in high cis-1,4-selective butadiene polymerization, Inorganica Chimica Acta, 2015, 436, 132-138.

8. Li W*, Guan C, Xu J, Mu JS, Gong DR, Chen ZR, Zhou Q, Disentangled uhmwpe/poss nanocomposites prepared by ethylene in situ polymerization, Polymer, 2014, 55, 1792-1798.

9. Li W*, Guan C, Xu J, Chen ZR, Jiang BB, Wang JD, Yang YR, bimodal/broad polyethylene prepared in a disentangled state, Industrial & Engineering Chemistry Research, 2014, 53, 1088-1096.

10. Mu JS*, Yang F, Li W, Gong DR, Liu ZS, Jiang F, Chen ZR, Synthesis of amphiphilic linear-hyperbranched graft-copolymers via grafting based on linear polyethylene backbone, Journal of Polymer Science Part A: Polymer Chemistry, 2014, 52, 2146-2154.

11. Guan C, Yang HQ, Li W*, Zhou DY, Xu J, Chen ZR, Crystallization behavior of ultrahigh-molecular-weight polyethylene/polyhedral oligomeric silsesquioxane nanocomposites prepared by ethylene in situ polymerization, Journal of Applied Polymer Science, 2014, 131, 40847.

12. Li W*, Hou Linxi, Chen Zhongren, An NMR investigation of phase structure and chain dynamics in the polyethylene/montmorillonite nanocomposites, Journal of Nanomaterials, 2013, 2013, 93702.

13. Li W*, Hou Linxi, Liu Yan, Chen Zhongren, Curing behavior and rheology properties of alkyl-imidazolium-treated rectorite/epoxy nanocomposites. Polymer Engineering and Science. 2012,11,1534-1541.

14. 吴晶，历伟，蒋斌波，王靖岱，阳永荣，无机/有机复合载体负载乙酰丙酮铁/双亚胺基吡啶催化剂及其乙烯聚合，高分子学报，2012，2：138-147

15. Li W, Jiang BB, Wang JD, Yang YR. Organic/inorganic support for immobilizing (n-Bucp)2zrcl2/ticl3 hybrid catalyst to prepare polymer blends. Polymer International, 2011, 60, 676-684.

16. Li W, Adams A, Wang JD, Blümich B, Yang YR. Polyethylene/palygorskite nanocomposites: preparation by in situ polymerization and their characterization. Polymer, 2010, 51, 4686-4697.

17. Li W, Adams A, Wang JD, Blümich B, Yang YR, Zheng J. An NMR investigation on the phase structure and molecular mobility of the novel exfoliated polyethylene/palygorskite nanocomposites. Journal of polymer science, part b: polymer physics, 2010, 48, 1363-1371.

1、负载型催化剂活性点位设计与超高分子量聚乙烯微观结构的调控（国家自然科学基金面上项目，青年基金21206078）

2、POSS分子表面迁移机理及其在尼龙6表面强化的应用（国家自然科学基金面上项目，青年基金51203081）

3、微化学环境下的乙烯原位聚合机理与双峰聚乙烯分子结构的调控（浙江省自然科学基金一般项目LQ12B06003）

4、无缠结超高分子量聚乙烯的制备（浙江省重点创新团队子课题，省级项目）

5、原位聚合制备无缠结超高分子量聚乙烯纳米复合材料（浙江省重点创新团队子课题，省级项目）

6、高分子材料成分剖析的逆向工程（企业横向课题）

培养研究生

在读研究生 姓名 研究方向

2014级 陈毓明（浙江大学联合培养博士生） 非均相催化

2015级 杨华琴 催化剂载体设计与UHMWPE的高性能化

2015级 张晶晶 高分子薄膜的表面强化

2016级 惠磊 高效Ziegler-Natta催化剂

毕业研究生

年级 姓名 毕业去向

2012级 关超 KAUST大学攻读博士，全额奖学金

2012级 徐杰 微宏动力系统（湖州）有限公司，产品研发

2013级 陈涛 宁波七诺新材料有限公司，产品研发

2013级 陈鹏 宁波敏实集团有限公司，产品研发

2014级 薛兵（福州大学联合培养硕士）药明康德（武汉）有限公司